1,3-Cationic Alkylidene Migration of Nonclassical Carbocation: A Density Functional Theory Study on Gold(I)-Catalyzed Cycloisomerization of 1,5-Enynes Containing Cyclopropene Moiety.
For quite a long time, nonclassical carbocations have only been regarded as special intermediates with limited cases in solvolysis reactions. However, the present work shows that in common reaction, typical nonclassical carbocations may be involved in and have significant effects on the reaction mec...
| Publicado en: | Journal of the American Chemical Society Vol. 136; no. 4; pp. 1505 - 1514 |
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| Autores principales: | , |
| Formato: | Artículo |
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American Chemical Society
1/29/2014
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| Acceso en línea: | Ver este registro en EBSCOhost |