BUTYRIC ACID INTERACTION WITH CARBON NANOTUBES: MODELING BY A SEMI-EMPIRICAL APPROACH.

The quantum interaction properties of the butyric acid radical on the side walls of the single walled carbon nanotubes (CNT) are modeled by PM3 calculations. It is found that the interaction potential of the butyric acid with the tubes forms stable complexes when it reacts with the carbon atom (C³-c...

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Publicado en:Revista Cubana de Física Vol. 30; no. 2; pp. 72 - 77
Autor principal: AL-ANBER, M. J.
Formato: Artículo
Publicado: Universidad de La Habana 2013
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Acceso en línea:Ver este registro en EBSCOhost
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        atl: BUTYRIC ACID INTERACTION WITH CARBON NANOTUBES: MODELING BY A SEMI-EMPIRICAL APPROACH.
      aug:
        au: AL-ANBER, M. J.
        affil: Computational Physics Molecular Lab., Department of Physics, College of Science, Basrah University, Basrah, Iraq
      su:
        Carbon nanotubes
        Binding energy
        Electronic structure
        Butyric acid
        Fatty acids
        Atoms
        Metastable states
      sug:
        subj:
          Carbon nanotubes
          Binding energy
          Electronic structure
          Butyric acid
          Fatty acids
          Atoms
          Metastable states
      ab:
        The quantum interaction properties of the butyric acid radical on the side walls of the single walled carbon nanotubes (CNT) are modeled by PM3 calculations. It is found that the interaction potential of the butyric acid with the tubes forms stable complexes when it reacts with the carbon atom (C³-centered) and metastable conformations with the C¹ and C² atoms. We have studied the effect of the diameter-length characteristics of the CNT on the binding with a fatty acid. Our results suggest that the binding energy decreases as the diameter increases, and it initially increases as the length increases.
        Se investigan, mediante cálculos PM3, las propiedades de interacción cuántica del radical de ácido butírico y las paredes laterales de nanotubos mono-pared. Se encuentra que el potencial de interacción del ácido butírico con los tubos forma complejos estables cuando reacciona con el átomo de carbono (C³-centrado), y configuraciones metaestables con los átomos C¹ y C². Hemos estudiado el efecto de las características diámetro-longitud del nanotubo de carbono en su enlace con un ácido graso. Nuestros resultados sugieren que la energía de enlace decrece al aumentar el diámetro, pero se incrementa al aumentar la longitud del nanotubo.
      pubtype: Academic Journal
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    language: English
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