The Reaction Rates of O with Closed-Shell and Open-Shell Al and Ga Clusters under Single-Collision Conditions: Experimental and Theoretical Investigations toward a Generally Valid Model for the Hindered Reactions of O with Metal Atom Clusters

In order to characterize the oxidation of metallic surfaces, the reactions of O with a number of Al and, for the first time, Ga clusters as molecular models have been investigated, and the results are presented here for x = 9-14. The rate coefficients were determined with FT-ICR mass spectrometry un...

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Publicado en:	Journal of the American Chemical Society Vol. 136; no. 9; pp. 3607 - 3617
Autores principales:	Neumaier, Marco, Olzmann, Matthias, Kiran, Boggavarapu, Bowen, Kit H., Eichhorn, Bryan, Stokes, Sarah T., Buonaugurio, Angela, Burgert, Ralf, Schnöckel, Hansgeorg
Formato:	Artículo
Publicado:	American Chemical Society 3/5/2014
Materias:	Chemical kinetics Oxygen Metal clusters Molecular models Reactivity (Chemistry) Aluminum Chlorine Density functional theory
Acceso en línea:	Ver este registro en EBSCOhost