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Empirical and Theoretical Insights into the Structural Features and Host-Guest Chemistry of ML Tube Architectures.

We demonstrate a general method for the construction of ML tubular complexes via subcomponent self-assembly, starting from Cu or Ag precursors together with suitable elongated tetraamine and 2-formylpyridine subcomponents. The tubular architectures were often observed as equilibrium mixtures of dias...

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Publicado en:Journal of the American Chemical Society Vol. 136; no. 10; pp. 3972 - 3981
Autores principales: Wenjing Meng, League, Aaron B., Ronson, Tanya K., Clegg, Jack K., Isley III, William C., Semrouni, David, Gagliardi, Laura, Cramer, Christopher J., Nitschke, Jonathan R.
Formato: Artículo
Publicado: American Chemical Society 3/12/2014
Materias:
Host-guest chemistry
Molecular self-assembly
Copper
Silver
Diastereoisomers
Equilibrium reactions
Substituents (Chemistry)
Density functional theory
Acceso en línea:Ver este registro en EBSCOhost