Redox-Neutral α-Oxygenation of Amines: Reaction Development and Elucidation of the Mechanism.

Cyclic secondary amines and 2-hydroxybenzal-dehydes or related ketones react to furnish benzo[e][l,3]- oxazine structures in generally good yields. This overall redox-neutral amine α-C-H functionalization features a combined reductive N-alkylation/oxidative a-functionalization and is catalyzed by ac...

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Publicado en:	Journal of the American Chemical Society Vol. 136; no. 16; pp. 6123 - 6136
Autores principales:	Richers, Matthew T., Breugst, Martin, Platonova, Alena Yu., Ullrich, Anja, Dieckmann, Arne, Houk, K. N., Seidel, Daniel
Formato:	Artículo
Publicado:	American Chemical Society 4/23/2014
Materias:	Amines Oxidation Secondary amines Reaction mechanisms (Chemistry) Density functional theory Amination kinetics Benzylamine Acetic acid analysis Catalytic activity
Acceso en línea:	Ver este registro en EBSCOhost