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Synthesis of an adj-Dicarbaporphyrin and the Formation of an Unprecedented Tripalladium Sandwich Complex.

An adj-dicarbaporphyrin was prepared by carrying out a base-catalyzed MacDonald reaction between bis(3-indenyl)methane and a dipyrrylmethane dialdehyde. The porphyrinoid system exhibited highly diatropic characteristics, and the proton NMR spectrum gave resonances at -5.74 and -6.24 ppm for the inte...

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Publicado en:Journal of the American Chemical Society Vol. 136; no. 18; pp. 6763 - 6773
Autores principales: AbuSalim, Deyaa I., Ferrence, Gregory M., Lash, Timothy D.
Formato: Artículo
Publicado: American Chemical Society 5/7/2014
Materias:
Palladium
Base catalysts
Methane
Nuclear magnetic resonance
Mesomerism
Cations
Trifluoroacetic acid
Density functional theory
Acceso en línea:Ver este registro en EBSCOhost