Highly Efficient Alkane Oxidation Catalyzed by [Mn(N)(CN)]. Evidence for [Mn(N)(O)(CN)] as an Active Intermediate.

The oxidation of various alkanes catalyzed by [Mn(N)(CN)] using various terminal oxidants at room temperature has been investigated. Excellent yields of alcohols and ketones (>95%) are obtained using HO as oxidant and CFCHOH as solvent. Good yields (>80%) are also obtained using (NH)2[Ce(NO)] in CFC...

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Publicado en:	Journal of the American Chemical Society Vol. 136; no. 21; pp. 7680 - 7688
Autores principales:	Li Ma, Yi Pan, Wai-Lun Man, Hoi-Ki Kwong, Lam, William W. Y., Gui Chen, Kai-Chung Lau, Tai-Chu Lau
Formato:	Artículo
Publicado:	American Chemical Society 5/28/2014
Materias:	Oxidation of alkanes Oxidation Manganese compounds Cyclohexane Density functional theory
Acceso en línea:	Ver este registro en EBSCOhost