Performance Evaluation of Currently Used Portable X ray Fluorescence Instruments for Measuring the Lead Content of Paint in Field Samples.

Field-portable X-ray fluorescence (FP-XRF) instruments are important for non-destructive, rapid and convenient measurements of lead in paint, in view of potential remediation. Using real-life paint samples, we compared measurements from three FP-XRF instruments currently used in Switzerland with lab...

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Publicado en:Journal of Occupational & Environmental Hygiene Vol. 11; no. 8; pp. 528 - 538
Autores principales: Muller, Yan, Favreau, Philippe, Kohler, Marcel
Formato: pictorial research tables/charts Journal Article
Publicado: Taylor & Francis Ltd Aug2014
Acceso en línea:Ver este registro en EBSCOhost
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      dt: Aug2014
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      pub: Taylor & Francis Ltd
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        10.1080/15459624.2014.880788
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        atl: Performance Evaluation of Currently Used Portable X ray Fluorescence Instruments for Measuring the Lead Content of Paint in Field Samples.
      aug:
        au:
          Muller, Yan
          Favreau, Philippe
          Kohler, Marcel
        affil: Départment de l'environnement, des transports et de l'agriculture, Direction générale de l'environnement, Service de Toxicologie de l'Environnement Bâti, Geneva, Switzerland
      sug:
        subj:
          Paint Switzerland
          Radiography
          Lead Analysis
          Human
          Mass Spectrometry
          Hazardous Materials
          Switzerland
          Construction Materials
          Education, Continuing (Credit)
      ab: Field-portable X-ray fluorescence (FP-XRF) instruments are important for non-destructive, rapid and convenient measurements of lead in paint, in view of potential remediation. Using real-life paint samples, we compared measurements from three FP-XRF instruments currently used in Switzerland with laboratory measurements using inductively coupled plasma mass spectrometry after complete sample dissolution. Two FP-XRF devices that functioned by lead L shell excitation frequently underestimated the lead concentration of samples. Lack of accuracy correlated with lead depth and/or the presence of additional metal elements (Zn, Ba or Ti). A radioactive source emitter XRF that enabled the additional K shell excitation showed higher accuracy and precision, regardless of the depth of the lead layer in the sample or the presence of other elements. Inspection of samples by light and electron microscopy revealed the diversity of real-life samples, with multi-layered paints showing various depths of lead and other metals. We conclude that the most accurate measurements of lead in paint are currently obtained with instruments that provide at least sufficient energy for lead K shell excitation.
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      ougenre: Article
    language: English
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