High Electrical Conductivity in Ni(2,3/6,7,10,11-hexaiminotriphenylene), a Semiconducting Metal-Organic Graphene Analogue.
Reaction of 2,3,6,7,10,11-hexaaminotriphenylene with Ni in aqueous NH solution under aerobic conditions produces Ni(HITP) (HITP = 2,3,6,7,10,11-hexaiminotriphenylene), a new two-dimensional metal—organic framework (MOF). The new material can be isolated as a highly conductive black powder or dark bl...
| Publicado en: | Journal of the American Chemical Society Vol. 136; no. 25; pp. 8859 - 8863 |
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| Autores principales: | , , , , , , , |
| Formato: | Artículo |
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American Chemical Society
6/25/2014
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| Materias: | |
| Acceso en línea: | Ver este registro en EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=96955124&site=ehost-live header: @attributes: shortDbName: hlh uiTerm: 96955124 longDbName: Humanities International Complete uiTag: AN controlInfo: bkinfo: jinfo: jid: 00027863 ACS jtl: Journal of the American Chemical Society issn: 00027863 maglogo: N pubinfo: dt: 6/25/2014 vid: 136 iid: 25 pid: 997 pub: American Chemical Society artinfo: ui: 96955124 10.1021/ja502765n ppf: 8859 ppct: 4 formats: tig: atl: High Electrical Conductivity in Ni(2,3/6,7,10,11-hexaiminotriphenylene), a Semiconducting Metal-Organic Graphene Analogue. aug: au: Sheberla, Dennis Lei Sun Blood-Forsythe, Martin A. Er, Süleyman Wade, Casey R. Brozek, Carl K. Aspuru-Guzik, Alán Dincă, Mircea affil: Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States Department of Chemistry & Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, United States su: Electrical conductivity measurement Electric conductivity Semiconductor devices Electrical conductors Semiconductor technology Metal-organic frameworks Structural frames Coordination polymers sug: subj: Electrical conductivity measurement Electric conductivity Semiconductor devices Electrical conductors Semiconductor technology Metal-organic frameworks Structural frames Coordination polymers ab: Reaction of 2,3,6,7,10,11-hexaaminotriphenylene with Ni in aqueous NH solution under aerobic conditions produces Ni(HITP) (HITP = 2,3,6,7,10,11-hexaiminotriphenylene), a new two-dimensional metal—organic framework (MOF). The new material can be isolated as a highly conductive black powder or dark blue-violet films. Two-probe and van der Pauw electrical measurements reveal bulk (pellet) and surface (film) conductivity values of 2 and 40 S•cm, respectively, both records for MOFs and among the best for any coordination polymer. pubtype: Academic Journal doctype: Article src: R language: English refInfo: copyright: @attributes: flag: Y dt: @attributes: year: 2014 holdings: @attributes: islocal: N |
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