A Combined Mössbauer, Magnetic Circular Dichroism, and Density Functional Theory Approach for Iron Cross-Coupling Catalysis: Electronic Structure, In Situ Formation, and Reactivity of Iron-Mesityl-Bisphosphines

While iron-bisphosphines have emerged as effective catalysts for C—C cross-coupling, the nature of the in situ formed iron species, elucidation of the active catalysts and the mechanisms of catalysis have remained elusive. A combination of Fe Mössbauer and magnetic circular dichroism (MCD) spectrosc...

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Publicado en:	Journal of the American Chemical Society Vol. 136; no. 25; pp. 9132 - 9144
Autores principales:	Daifuku, Stephanie L., Al-Afyouni, Malik H., Snyder, Benjamin E. R., Kneebone, Jared L., Neidig, Michael L.
Formato:	Artículo
Publicado:	American Chemical Society 6/25/2014
Materias:	Iron compounds Diphosphine Mössbauer spectroscopy Magnetic circular dichroism Density functional theory Coupling reactions (Chemistry) Electronic structure Reaction mechanisms (Chemistry)
Acceso en línea:	Ver este registro en EBSCOhost