Mechanism of the Electrocatalytic Reduction of Protons with Diaryldithiolene Cobalt Complexes.

A series of dimeric cobalt-diaryldithiolene complexes [Co(SCAr)], possessing various aryl para substituents (OMe, F, Cl, and Br), were studied as electrocatalysts for proton reduction in nonaqueous media, in an effort to correlate dithiolene donor strength with catalyst activity. Cyclic voltammetry...

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Publicado en:	Journal of the American Chemical Society Vol. 136; no. 26; pp. 9364 - 9377
Autores principales:	Letko, Christopher S., Panetier, Julien A., Head-Gordon, Martin, Tilley, T. Don
Formato:	Artículo
Publicado:	American Chemical Society 7/2/2014
Materias:	Electrocatalysis Chemical reduction Cobalt compounds Protons Aromatic compounds Cyclic voltammetry Monomers Density functional theory
Acceso en línea:	Ver este registro en EBSCOhost