Spectroscopic Characterization and Reactivity Studies of a Mononuclear Nonheme Mn(lll)-Hydroperoxo Complex.

We report the first example of a mononuclear nonheme manganese(III)-hydroperoxo complex derived from protonation of an isolated manganese(III)—peroxo complex bearing an N-tetramethylated cyclam (TMC) ligand, [Mn(TMC)(OOH)]. The Mn-hydroperoxo intermediate is characterized with various spectroscopic...

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Detalles Bibliográficos

Publicado en:	Journal of the American Chemical Society Vol. 136; no. 35; pp. 12229 - 12233
Autores principales:	Hee So, Young Jun Park, Kyung-Bin Cho, Yong-Min Lee, Mi Sook Seo, Jaeheung Cho, Sarangi, Ritimukta, Wonwoo Nam
Formato:	Artículo
Publicado:	American Chemical Society 9/3/2014
Materias:	Reactivity (Chemistry) Manganese compounds Proton transfer reactions Intermediates (Chemistry) Electrophiles Oxidizing agents Ligands (Chemistry) Density functional theory
Acceso en línea:	Ver este registro en EBSCOhost