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Mechanism of Alcohol Oxidation Mediated by Copper(ll) and Nitroxyl Radicals.

2,2'-Bipyridine-ligated copper complexes, in combination with TEMPO (2,2,6,6-tetramethylpiperidine-N-oxyl), are highly effective catalysts for aerobic alcohol oxidation. Considerable uncertainty and debate exist over the mechanism of alcohol oxidation mediated by Cu and TEMPO. Here, we report experi...

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Publicado en:Journal of the American Chemical Society Vol. 136; no. 34; pp. 12166 - 12174
Autores principales: Ryland, Bradford L., McCann, Scott D., Brunold, Thomas C., Stahl, Shannon S.
Formato: Artículo
Publicado: American Chemical Society 8/27/2014
Materias:
Alcohol oxidation
Copper
Nitroxyl
Radicals (Chemistry)
Density functional theory
Alkoxides
Hydrogen transfer reactions
Reactivity (Chemistry)
Acceso en línea:Ver este registro en EBSCOhost