Trimethyltin-Mediated Covalent Gold-Carbon Bond Formation.

We study the formation of covalent gold-carbon bonds in benzyltrimethylstannane (CHSn) deposited on Au in ultra-high-vacuum conditions. Through X-ray photoemission spectroscopy and X-ray absorption measurements, we find that the molecule fragments at the Sn—benzyl bond when exposed to Au surfaces at...

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Publicado en:	Journal of the American Chemical Society Vol. 136; no. 36; pp. 12556 - 12560
Autores principales:	Batra, Arunabh, Kladnik, Gregor, Gorjizadeh, Narjes, Meisner, Jeffrey, Steigerwald, Michael, Nuckolls, Colin, Su Ying Quek, Cvetko, Dean, Morgante, Alberto, Venkataraman, Latha
Formato:	Artículo
Publicado:	American Chemical Society 9/10/2014
Materias:	Chemical bonds Gold Carbon Benzyl compounds Photoelectron spectroscopy
Acceso en línea:	Ver este registro en EBSCOhost