An Intermediate Cobalt(IV) Nitrido Complex and its N-Migratory Insertion Product.

Low-temperature photolysis experiments (T = 10 K) on the tripodal azido complex [(BIMPN)Co(N)] ( l) were monitored by EPR spectroscopy and support the formation of an exceedingly reactive, high-valent Co nitrido species [(BIMPN)Co (N)] (2). Density functional theory calculations suggest a low-spin d...

Descripción completa

Detalles Bibliográficos

Publicado en:	Journal of the American Chemical Society Vol. 136; no. 42; pp. 15072 - 15079
Autores principales:	Zolnhofer, Eva M., Käβ, Martina, Khusniyarov, Marat M., Heinemann, Frank W., Maron, Laurent, van Gaste, Maurice, Bill, Eckhard, Meyer, Karsten
Formato:	Artículo
Publicado:	American Chemical Society 10/22/2014
Materias:	Photolysis (Chemistry) Azido group Electron paramagnetic resonance spectroscopy Density functional theory Nitrides
Acceso en línea:	Ver este registro en EBSCOhost