Reaction Mechanism of the Anomalous Formal Nucleophilic Borylation of Organic Halides with Silylborane: Combined Theoretical and Experimental Studies.

Theoretical and experimental studies have been conducted to elucidate the mechanism of the formal nucleophilic boryl substitution of aryl and alkyl bromides with silylborane in the presence of potassium methoxide. Density functional theory was used in conjunction with the artificial force induced re...

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Publicado en:	Journal of the American Chemical Society Vol. 137; no. 12; pp. 4090 - 4100
Autores principales:	Ryohei Uematsu, Eiji Yamamoto, Satoshi Maeda, Hajime Ito, Tetsuya Taketsugu
Formato:	Artículo
Publicado:	American Chemical Society 4/1/2015
Materias:	Nucleophilic reactions Alkyl bromides Potassium Density functional theory Carbanions
Acceso en línea:	Ver este registro en EBSCOhost