Reaction Mechanism of the Anomalous Formal Nucleophilic Borylation of Organic Halides with Silylborane: Combined Theoretical and Experimental Studies.

Theoretical and experimental studies have been conducted to elucidate the mechanism of the formal nucleophilic boryl substitution of aryl and alkyl bromides with silylborane in the presence of potassium methoxide. Density functional theory was used in conjunction with the artificial force induced re...

Full description

Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 137; no. 12; pp. 4090 - 4100
Main Authors:	Ryohei Uematsu, Eiji Yamamoto, Satoshi Maeda, Hajime Ito, Tetsuya Taketsugu
Format:	Article
Published:	American Chemical Society 4/1/2015
Subjects:	Nucleophilic reactions Alkyl bromides Potassium Density functional theory Carbanions
Online Access:	View this record in EBSCOhost