Catalytic Enantioselective Intermolecular Desymmetrization of Azetidines.

The first catalytic asymmetric desymmetrization of azetidines is disclosed. Despite the low propensity of azetidine ring opening and challenging stereocontrol, smooth intermolecular reactions were realized with excellent efficiency and enantioselectivity. These were enabled by the suitable combinati...

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Publicado en:	Journal of the American Chemical Society Vol. 137; no. 18; pp. 5895 - 5899
Autores principales:	Zhaobin Wang, Fu Kit Sheong, Sung, Herman H. Y., Williams, Ian D., Zhenyang Lin, Jianwei Sun
Formato:	Artículo
Publicado:	American Chemical Society 5/13/2015
Materias:	Enantioselective catalysis Azetidine Density functional theory Curtin-Hammett principle Amine derivatives
Acceso en línea:	Ver este registro en EBSCOhost