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Mechanistic Insight into Ketone α-Alkylation with Unactivated Olefins via C-H Activation Promoted by Metal-Organic Cooperative Catalysis (MOCC): Enriching the MOCC Chemistry.

Metal-organic cooperative catalysis (MOCC) has been successfully applied for hydroacylation of olefins with aldehydes via directed C(sp ²)-H functionalization. Most recently, it was reported that an elaborated MOCC system, containing Rh(I) catalyst and 7-azaindoline (L1) cocatalyst, could even catal...

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Publicado en:Journal of the American Chemical Society Vol. 137; no. 19; pp. 6279 - 6292
Autores principales: Yanfeng Dang, Shuanglin Qu, Yuan Tao, Xi Deng, Zhi-Xiang Wang
Formato: Artículo
Publicado: American Chemical Society 5/20/2015
Materias:
Ketone synthesis
Alkylation
Alkenes
Carbon-hydrogen bonds
Organometallic compounds
Density functional theory
Acceso en línea:Ver este registro en EBSCOhost