Mechanistic Insight into Ketone α-Alkylation with Unactivated Olefins via C-H Activation Promoted by Metal-Organic Cooperative Catalysis (MOCC): Enriching the MOCC Chemistry.

Metal-organic cooperative catalysis (MOCC) has been successfully applied for hydroacylation of olefins with aldehydes via directed C(sp ²)-H functionalization. Most recently, it was reported that an elaborated MOCC system, containing Rh(I) catalyst and 7-azaindoline (L1) cocatalyst, could even catal...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 137; no. 19; pp. 6279 - 6292
Main Authors:	Yanfeng Dang, Shuanglin Qu, Yuan Tao, Xi Deng, Zhi-Xiang Wang
Format:	Article
Published:	American Chemical Society 5/20/2015
Subjects:	Ketone synthesis Alkylation Alkenes Carbon-hydrogen bonds Organometallic compounds Density functional theory
Online Access:	View this record in EBSCOhost