Reaction of Cp*(CI)M(Diene) (M = Ti, Hf) with Isonitriles.
We have investigated the reaction of isonitriles (RNC) with electronically unsaturated diene complexes of Ti and Hf. Cp*(Cl)Ti(2,3-dimethylbutadiene) (1) reacts with 2 equiv of RNC to give η,η-diimine complexes 2 (R = Bu) and 3 (R = 1-adamantyl). Cp*(Cl)Ti(N,N-di-Bu-η,η-diimine) (2), in the presence...
| Publicado en: | Journal of the American Chemical Society Vol. 137; no. 32; pp. 10152 - 10156 |
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| Autores principales: | , , |
| Formato: | Artículo |
| Publicado: |
American Chemical Society
8/19/2015
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| Materias: | |
| Acceso en línea: | Ver este registro en EBSCOhost |