Reaction of Cp*(CI)M(Diene) (M = Ti, Hf) with Isonitriles.

We have investigated the reaction of isonitriles (RNC) with electronically unsaturated diene complexes of Ti and Hf. Cp*(Cl)Ti(2,3-dimethylbutadiene) (1) reacts with 2 equiv of RNC to give η,η-diimine complexes 2 (R = Bu) and 3 (R = 1-adamantyl). Cp*(Cl)Ti(N,N-di-Bu-η,η-diimine) (2), in the presence...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 137; no. 32; pp. 10152 - 10156
Main Authors:	Valadez, Travis N., Norton, Jack R., Neary, Michelle C.
Format:	Article
Published:	American Chemical Society 8/19/2015
Subjects:	Isocyanides Diolefins Pyridine Hafnium Cyclopropanation
Online Access:	View this record in EBSCOhost