Dearomative Indole (3 + 2) Reactions with Azaoxyallyl Cations -- New Method for the Synthesis of Pyrroloindolines.
Herein, we report the first examples of the synthesis of pyrroloindolines by means of (3 + 2) dearomative annulation reactions between 3-substituted indoles and highly reactive azaoxyallyl cations. Computational studies using density functional theory (DFT) (B3LYP-D3/6-311G**++) support a stepwise r...
| Publicado en: | Journal of the American Chemical Society Vol. 137; no. 47; pp. 14861 - 14865 |
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| Autores principales: | , , |
| Formato: | Artículo |
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American Chemical Society
12/2/2015
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| Acceso en línea: | Ver este registro en EBSCOhost |