Isolation of Hypervalent Group-16 Radicals and Their Application in Organic-Radical Batteries.

Using a newly prepared tridentate ligand, we isolated hypervalent sulfur and selenium radicals for the first time and characterized their structures. X-ray crystallography, electron spin resonance spectroscopy, and density functional theory calculations revealed a three-coordinate hypervalent struct...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 138; no. 2; pp. 479 - 483
Main Authors:	Yasuyuki Imada, Hideyuki Nakano, Ko Furukawa, Ryohei Kishi, Masayoshi Nakano, Hitoshi Marayama, Masaaki Nakamoto, Akira Sekiguchi, Masahiro Ogawa, Toshiaki Ohta, Yohsuke Yamamoto
Format:	Article
Published:	American Chemical Society 1/20/2016
Subjects:	Hypervalence (Theoretical chemistry) Electron paramagnetic resonance Density functionals Oxidation-reduction reaction Cathodes Silyl radicals
Online Access:	View this record in EBSCOhost