Surface-Controlled Mono/Diselective ortho C-H Bond Activation.

One of the most charming and challenging topics in organic chemistry is the selective C-H bond activation. The difficulty arises not only from the relatively large bond-dissociation enthalpy, but also from the poor reaction selectivity. In this work, Au(111) and Ag(111) surfaces were used to address...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 138; no. 8; pp. 2809 - 2815
Main Authors:	Qing Li, Biao Yang, Haiping Lin, Nabi Aghdassi, Kangjian Miao, Junjie Zhang, Haiming Zhang, Youyong Li, Steffen Duhm, Jian Fan, Lifeng Chi
Format:	Article
Published:	American Chemical Society 3/2/2016
Subjects:	Carbon-hydrogen bonds Dehydrogenation kinetics Density functional theory Organic synthesis Oxidation of phenol
Online Access:	View this record in EBSCOhost