[Pd(μ-SbMe)(SbMe)]: A Pd(0) Tetrahedron with μ-Bridging Trimethylantimony Ligands.

The palladium(II) chlorostibine complex [PdCl(SbMeCl)] has a dimeric structure in the solid state, stabilized by hyper-coordination at the Lewis amphoteric Sb centers. Reaction with 8 equiv of MeLi forms [Pd(μ-SbMe)(SbMe)], whose structure comprises a tetrahedral Pd(0) core with four terminal SbMe l...

Descripción completa

Detalles Bibliográficos

Publicado en:	Journal of the American Chemical Society Vol. 138; no. 22; pp. 6964 - 6968
Autores principales:	Benjamin, Sophie L., Krämer, Tobias, Levason, William, Light, Mark E., Macgregor, Stuart A., Reid, Gillian
Formato:	Artículo
Publicado:	American Chemical Society 6/8/2016
Materias:	Palladium Tetrahedra Lewis bases Density functional theory Ligands (Chemistry) Coordination compounds Ligand exchange reactions
Acceso en línea:	Ver este registro en EBSCOhost