[Pd(μ-SbMe)(SbMe)]: A Pd(0) Tetrahedron with μ-Bridging Trimethylantimony Ligands.
The palladium(II) chlorostibine complex [PdCl(SbMeCl)] has a dimeric structure in the solid state, stabilized by hyper-coordination at the Lewis amphoteric Sb centers. Reaction with 8 equiv of MeLi forms [Pd(μ-SbMe)(SbMe)], whose structure comprises a tetrahedral Pd(0) core with four terminal SbMe l...
| Publicado en: | Journal of the American Chemical Society Vol. 138; no. 22; pp. 6964 - 6968 |
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| Autores principales: | , , , , , |
| Formato: | Artículo |
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American Chemical Society
6/8/2016
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| Materias: | |
| Acceso en línea: | Ver este registro en EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=116286866&site=ehost-live header: @attributes: shortDbName: hlh uiTerm: 116286866 longDbName: Humanities International Complete uiTag: AN controlInfo: bkinfo: jinfo: jid: 00027863 ACS jtl: Journal of the American Chemical Society issn: 00027863 maglogo: N pubinfo: dt: 6/8/2016 vid: 138 iid: 22 pid: 997 pub: American Chemical Society artinfo: ui: 116286866 10.1021/jacs.6b04060 ppf: 6964 ppct: 4 formats: tig: atl: [Pd(μ-SbMe)(SbMe)]: A Pd(0) Tetrahedron with μ-Bridging Trimethylantimony Ligands. aug: au: Benjamin, Sophie L. Krämer, Tobias Levason, William Light, Mark E. Macgregor, Stuart A. Reid, Gillian affil: School of Science and Technology, Nottingham Trent University, Nottingham NG11 8NS, United Kingdom Institute of Chemical Sciences, Heriot-Watt University, Edinburgh EH14 4AS, United Kingdom School of Chemistry, University of Southampton, Southampton SO17 1BJ, United Kingdom su: Palladium Tetrahedra Lewis bases Density functional theory Ligands (Chemistry) Coordination compounds Ligand exchange reactions sug: subj: Palladium Tetrahedra Lewis bases Density functional theory Ligands (Chemistry) Coordination compounds Ligand exchange reactions ab: The palladium(II) chlorostibine complex [PdCl(SbMeCl)] has a dimeric structure in the solid state, stabilized by hyper-coordination at the Lewis amphoteric Sb centers. Reaction with 8 equiv of MeLi forms [Pd(μ-SbMe)(SbMe)], whose structure comprises a tetrahedral Pd(0) core with four terminal SbMe ligands and four μ-SbMe ligands, one capping each triangular Pd face. Density functional theory calculations, supported by energy decomposition analysis and the natural orbitals for chemical valence scheme, highlight significant donor and acceptor orbital contributions to the bonding between both the terminal and the bridging SbMe ligands and the Pd core. pubtype: Academic Journal doctype: Article src: R language: English refInfo: copyright: @attributes: flag: Y dt: @attributes: year: 2016 holdings: @attributes: islocal: N |
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