Conjugation-Driven "Reverse Mars-van Krevelen"-Type Radical Mechanism for Low-Temperature C-O Bond Activation.

C-O bond activation on monofunctional catalysts (metals, carbides, and oxides) is challenging due to activity constraints imposed by energy scaling relationships. Yet, contrary to predictions, recently discovered multifunctional metal/metal oxide catalysts (e.g., Rh/ReO, Rh/MoO, Ir/VO) demonstrate u...

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Detalles Bibliográficos

Publicado en:	Journal of the American Chemical Society Vol. 138; no. 26; pp. 8104 - 8114
Autores principales:	Mironenko, Alexander V., Vlachos, Dionisios G.
Formato:	Artículo
Publicado:	American Chemical Society 7/6/2016
Materias:	Carbon monoxide Catalysts Metallic oxides Density functional theory Oxygen
Acceso en línea:	Ver este registro en EBSCOhost