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Conjugation-Driven "Reverse Mars-van Krevelen"-Type Radical Mechanism for Low-Temperature C-O Bond Activation.

C-O bond activation on monofunctional catalysts (metals, carbides, and oxides) is challenging due to activity constraints imposed by energy scaling relationships. Yet, contrary to predictions, recently discovered multifunctional metal/metal oxide catalysts (e.g., Rh/ReO, Rh/MoO, Ir/VO) demonstrate u...

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Published in:Journal of the American Chemical Society Vol. 138; no. 26; pp. 8104 - 8114
Main Authors: Mironenko, Alexander V., Vlachos, Dionisios G.
Format: Article
Published: American Chemical Society 7/6/2016
Subjects:
Carbon monoxide
Catalysts
Metallic oxides
Density functional theory
Oxygen
Online Access:View this record in EBSCOhost

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