Spectroscopic and Computational Investigations of a Mononuclear Manganese(IV)-Oxo Complex Reveal Electronic Structure Contributions to Reactivity.

The mononuclear Mn(IV)-oxo complex [Mn(O)(N4py)], where N4py is the pentadentate ligand N,N-bis(2-pyridylmethyl)-N-bis(2-pyridyl)methylamine, has been proposed to attack C-H bonds by an excited-state reactivity pattern [Cho, K.-B.; Shaik, S.; Nam, W. J. Phys. Chem. Lett. 2012, 3, 2851-2856 (DOI: 10....

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Publicado en:	Journal of the American Chemical Society Vol. 138; no. 47; pp. 15413 - 15425
Autores principales:	Leto, Domenick F., Massie, Allyssa A., Rice, Derek B., Jackson, Timothy A.
Formato:	Artículo
Publicado:	American Chemical Society 11/30/2016
Materias:	Ligands (Chemistry) Carbon-hydrogen bonds Density functional theory Magnetic circular dichroism Circular dichroism
Acceso en línea:	Ver este registro en EBSCOhost