Rationalization of Anomalous Pseudocontact Shifts and Their Solvent Dependence in a Series of C-Symmetric Lanthanide Complexes.

Bleaney's long-standing theory of magnetic anisotropy has been employed with some success for many decades to explain paramagnetic NMR pseudocontact shifts, and has been the subject of many subsequent approximations. Here, we present a detailed experimental and theoretical investigation accounting f...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 139; no. 40; pp. 14166 - 14173
Main Authors:	Vonci, Michele, Mason, Kevin, Suturina, Elizaveta A., Frawley, Andrew T., Worswick, Steven G., Kuprov, Ilya, Parker, David, McInnes, Eric J. L., Chilton, Nicholas F.
Format:	Article
Published:	American Chemical Society 10/11/2017
Subjects:	Magnetic anisotropy Rare earth metals Magnetic susceptibility Magnetic resonance Triazacyclononane Electronic structure
Online Access:	View this record in EBSCOhost