Arylketone π-Conjugation Controls Enantioselectivity in Asymmetric Alkynylations Catalyzed by Centrochiral Ruthenium Complexes.

The origin of enantioselectivity in the asymmetric alkynylation of trihalomethyl ketones catalyzed by octahedral stereogenic-at-ruthenium complexes has been investigated through density functional theory calculations. Computational results support a mechanism involving formation of a ruthenium acety...

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Publicado en:	Journal of the American Chemical Society Vol. 140; no. 15; pp. 5146 - 5153
Autores principales:	Shuming Chen, Yu Zheng, Tianjiao Cui, Meggers, Eric, Houk, K. N.
Formato:	Artículo
Publicado:	American Chemical Society 4/18/2018
Materias:	Bioconjugates Enantioselective catalysis Ruthenium compounds Ketones Density functional theory
Acceso en línea:	Ver este registro en EBSCOhost