Identification of the Formal +2 Oxidation State of Neptunium: Synthesis and Structural Characterization of {Np[CH(SiMe)]}.
We report a new formal oxidation state for neptunium in a crystallographically characterizable molecular complex, namely Np in [K(crypt)][NpCp″] [crypt = 2.2.2-cryptand, Cp″ = CH(SiMe)]. Density functional theory calculations indicate that the ground state electronic configuration of the Np2+ ion in...
| Publicado en: | Journal of the American Chemical Society Vol. 140; no. 24; pp. 7425 - 7429 |
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| Autores principales: | , , , , , , , , , |
| Formato: | Artículo |
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American Chemical Society
6/20/2018
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| Materias: | |
| Acceso en línea: | Ver este registro en EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=130322012&site=ehost-live header: @attributes: shortDbName: hlh uiTerm: 130322012 longDbName: Humanities International Complete uiTag: AN controlInfo: bkinfo: jinfo: jid: 00027863 ACS jtl: Journal of the American Chemical Society issn: 00027863 maglogo: N pubinfo: dt: 6/20/2018 vid: 140 iid: 24 pid: 997 pub: American Chemical Society artinfo: ui: 130322012 10.1021/jacs.8b03907 ppf: 7425 ppct: 4 formats: tig: atl: Identification of the Formal +2 Oxidation State of Neptunium: Synthesis and Structural Characterization of {Np[CH(SiMe)]}. aug: au: Jing Su Windorff, Cory J. Batista, Enrique R. Evans, William J. Gaunt, Andrew J. Janicke, Michael T. Kozimor, Stosh A. Scott, Brian L. Woen, David H. Ping Yang affil: Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, United States Chemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, United States Department of Chemistry, University of California-Irvine, Irvine, California 92697-2025, United States Materials Physics and Applications Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, United States su: Neptunium Crystallography Electron configuration Oxidation states Density functional theory sug: subj: Neptunium Crystallography Electron configuration Oxidation states Density functional theory ab: We report a new formal oxidation state for neptunium in a crystallographically characterizable molecular complex, namely Np in [K(crypt)][NpCp″] [crypt = 2.2.2-cryptand, Cp″ = CH(SiMe)]. Density functional theory calculations indicate that the ground state electronic configuration of the Np2+ ion in the complex is 5f6d. pubtype: Academic Journal doctype: Article src: R language: English refInfo: copyright: @attributes: flag: Y dt: @attributes: year: 2018 holdings: @attributes: islocal: N |
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