Identification of the Formal +2 Oxidation State of Neptunium: Synthesis and Structural Characterization of {Np[CH(SiMe)]}.
We report a new formal oxidation state for neptunium in a crystallographically characterizable molecular complex, namely Np in [K(crypt)][NpCp″] [crypt = 2.2.2-cryptand, Cp″ = CH(SiMe)]. Density functional theory calculations indicate that the ground state electronic configuration of the Np2+ ion in...
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| Publicado en: | Journal of the American Chemical Society
Vol. 140; no. 24; pp. 7425 - 7429 |
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| Autores principales: |
Jing Su,
Windorff, Cory J.,
Batista, Enrique R.,
Evans, William J.,
Gaunt, Andrew J.,
Janicke, Michael T.,
Kozimor, Stosh A.,
Scott, Brian L.,
Woen, David H.,
Ping Yang |
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| Formato: | Artículo
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| Publicado: |
American Chemical Society
6/20/2018
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| Acceso en línea: | Ver este registro en EBSCOhost
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