Mechanism of Ti-Catalyzed Oxidative Nitrene Transfer in [2 + 2 + 1] Pyrrole Synthesis from Alkynes and Azobenzene.
A combined computational and experimental study on the mechanism of Ti-catalyzed formal [2 + 2 + 1] pyrrole synthesis from alkynes and aryl diazenes is reported. This reaction proceeds through a formally Ti/Ti redox catalytic cycle as determined by natural bond orbital (NBO) and intrinsic bond orbit...
| Publicado en: | Journal of the American Chemical Society Vol. 140; no. 23; pp. 7267 - 7282 |
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| Autores principales: | , , , |
| Formato: | Artículo |
| Publicado: |
American Chemical Society
6/13/2018
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| Acceso en línea: | Ver este registro en EBSCOhost |