New dihydrobenzofuranoid from the marine-derived fungus Aspergillus ustus KMM 4664.

One new dihydrobenzofuran derivative (1), known depsipeptide emericellamide A (2), three known drimanes (3–5) and two artifact drimane derivatives (6, 7) were isolated from the marine-derived fungus Aspergillus ustus KMM 4664. Their structures were determined by detailed analysis of spectroscopic da...

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Publicado en:Natural Product Research Vol. 35; no. 19; pp. 3332 - 3336
Autores principales: Oleinikova, Galina K., Zhuravleva, Olesya I., Berdyshev, Dmitrii V., Menzorova, Natalia I., Popov, Roman S., Denisenko, Vladimir A., Kirichuk, Natalya N., Afiyatullov, Shamil Sh.
Formato: Journal Article
Publicado: Taylor & Francis Ltd Oct2021
Acceso en línea:Ver este registro en EBSCOhost
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      dt: Oct2021
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        10.1080/14786419.2019.1689496
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        atl: New dihydrobenzofuranoid from the marine-derived fungus Aspergillus ustus KMM 4664.
      aug:
        au:
          Oleinikova, Galina K.
          Zhuravleva, Olesya I.
          Berdyshev, Dmitrii V.
          Menzorova, Natalia I.
          Popov, Roman S.
          Denisenko, Vladimir A.
          Kirichuk, Natalya N.
          Afiyatullov, Shamil Sh.
        affil: Laboratory of Chemistry of Microbial Metabolites, G.B. Elyakov Pacific Institute of Bioorganic Chemistry, Vladivostok, Russian Federation
      sug:
      ab: One new dihydrobenzofuran derivative (1), known depsipeptide emericellamide A (2), three known drimanes (3–5) and two artifact drimane derivatives (6, 7) were isolated from the marine-derived fungus Aspergillus ustus KMM 4664. Their structures were determined by detailed analysis of spectroscopic data and by comparison with related known compounds. The absolute configuration of 1 was determined by time-dependent density functional theory (TD-DFT) calculations of ECD spectra. Compound 7 showed significant ability of the inhibition of spermatozoa to fertilize egg-cells of the sea urchin Strongylocentrotus intermedius with IC50 value 21 µM.
      pubtype: Academic Journal
      doctype: Journal Article
      ougenre: Article
    language: English
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