Chiroptical and Computational Studies of a Bridled Chiroporphyrin and of Its Nickel(II), Copper(II), and Zinc(II) Complexes.

Circular dichroism (CD) spectra and density functional theory (DFT) calculations are reported for a series of conformationally bistable chiroporphyrins with 8-methylene bridles MBCP-8, which can display either an αααα or an αβαβ orientation of their meso substituents. From DFT geometry optimizations...

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Publicado en:	Journal of the American Chemical Society Vol. 128; no. 19; pp. 6347 - 6357
Autores principales:	Maheut, Geraldine, Castaings, Anna, Pëcaut, Jacques, Daku, Latévi Max Lawson, Pesciteili, Gennaro, Di Bari, Lorenzo, Marchon, Jean-Claude
Formato:	Artículo
Publicado:	American Chemical Society 5/17/2006
Materias:	Circular dichroism Density functionals Nickel compounds Copper compounds Zinc compounds Carbenes
Acceso en línea:	Ver este registro en EBSCOhost