Hydrogen and Deuterium Atoms in OctasiIsesquioxanes: Experimental and Computational Studies.

The rate of detrapping of atomic hydrogen from several octasilsesquioxanes is the same for dissolved and solid samples and is independent of the presence of other species such as free radicals or oxygen; varying the cage substituents leads to only minor differences in the activation parameters. Hydr...

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Bibliographic Details
Published in:Journal of the American Chemical Society Vol. 128; no. 18; pp. 6111 - 6126
Main Authors: Päch, Michael, Macrae, Roderick M., Carmichael, Ian
Format: Article
Published: American Chemical Society 5/10/2006
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Online Access:View this record in EBSCOhost