Evidence for Two Ferryl Species in Chioroperoxidase Compound II.

Using a combination of density functional calculations and Mössbauer spectroscopy, we have examined chloroperoxidase compound II (CPO-II). The Mössbauer spectrum of CPO-ll suggests the presence of two distinct ferryl species in an ~70:30 ratio. Density functional calculations and cryogenic reduction...

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Publicado en:	Journal of the American Chemical Society Vol. 128; no. 18; pp. 6147 - 6154
Autores principales:	Stone, Karl L., Hoffart, Lee M., Behan, Rachel K., Krebs, Carsten, Green, Michael T.
Formato:	Artículo
Publicado:	American Chemical Society 5/10/2006
Materias:	Peroxidase Iron compounds Mössbauer spectroscopy Chlorine compounds Density functionals Hydrogen-ion concentration
Acceso en línea:	Ver este registro en EBSCOhost