A New Class of Mixed-Valence Systems with Orbitally Degenerate Organic Redox Centers. Examples Based on Hexa-Rhenium Molecular Prisms.
The article presents information on mixed-valence (MV) systems with orbitally degenerate organic redox centers. The most common examples of MV systems are of the type Mn-bridge, where M is a transition metal and the bridge is an organic linker. The excited-state calculations carried out for a nearly...
| Publicado en: | Journal of the American Chemical Society Vol. 128; no. 39; pp. 12592 - 12594 |
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| Autores principales: | , , , |
| Formato: | Artículo |
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American Chemical Society
10/4/2006
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| Materias: | |
| Acceso en línea: | Ver este registro en EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=22738884&site=ehost-live header: @attributes: shortDbName: hlh uiTerm: 22738884 longDbName: Humanities International Complete uiTag: AN controlInfo: bkinfo: jinfo: jid: 00027863 ACS jtl: Journal of the American Chemical Society issn: 00027863 maglogo: N pubinfo: dt: 10/4/2006 vid: 128 iid: 39 pid: 997 pub: American Chemical Society artinfo: ui: 22738884 10.1021/ja0623764 ppf: 12592 ppct: 2 formats: tig: atl: A New Class of Mixed-Valence Systems with Orbitally Degenerate Organic Redox Centers. Examples Based on Hexa-Rhenium Molecular Prisms. aug: au: Dinolfo, Peter H. Coropceanu, Veaceslav Brédas, Jean-Luc Hupp, Joseph T. affil: Department of Chemistry, Stanford University, Stanford, CA 94306. School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia 30332. Department of Chemistry, Northwestern University, Evanston, Illinois 60208. su: Valence fluctuations Oxidation-reduction reaction Transition metals Linkers (Computer programs) sug: subj: Valence fluctuations Oxidation-reduction reaction Transition metals Linkers (Computer programs) ab: The article presents information on mixed-valence (MV) systems with orbitally degenerate organic redox centers. The most common examples of MV systems are of the type Mn-bridge, where M is a transition metal and the bridge is an organic linker. The excited-state calculations carried out for a nearly trigonal symmetry of the model system indicate some build up of IT character and an increase in intensity for other transitions. pubtype: Academic Journal doctype: Article src: R language: English refInfo: copyright: @attributes: flag: Y dt: @attributes: year: 2006 holdings: @attributes: islocal: N |
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