Pentaindenocorannulene and Tetraindenocorannulene: New Aromatic Hydrocarbon π Systems with Curvatures Surpassing That of C.
The article reports the new aromatic π systems, Pentaindenocorannulene and Tetraindenocorannulene. The procedures in the syntheses of the two new geodesic polyarenes are the same except in their starting organic compounds. The X-ray crystal structures and the degree of pyramidization were also exami...
| Publicado en: | Journal of the American Chemical Society Vol. 129; no. 3; pp. 484 - 486 |
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| Autores principales: | , , , , |
| Formato: | Artículo |
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American Chemical Society
1/24/2007
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| Materias: | |
| Acceso en línea: | Ver este registro en EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=23838735&site=ehost-live header: @attributes: shortDbName: hlh uiTerm: 23838735 longDbName: Humanities International Complete uiTag: AN controlInfo: bkinfo: jinfo: jid: 00027863 ACS jtl: Journal of the American Chemical Society issn: 00027863 maglogo: N pubinfo: dt: 1/24/2007 vid: 129 iid: 3 pid: 997 pub: American Chemical Society artinfo: ui: 23838735 10.1021/ja067487h ppf: 484 ppct: 2 formats: tig: atl: Pentaindenocorannulene and Tetraindenocorannulene: New Aromatic Hydrocarbon π Systems with Curvatures Surpassing That of C. aug: au: Jackson, Edward A. Steinberg, Brian D. Bancu, Mihail Wakamiya, Atsushi Scott, Lawrence T. affil: Merkert Chemistry Center, Department of Chemistry, Boston College, Chestnut Hill, Massachusetts 02467-3860 Department of Chemistry, Graduate School of Science, Nagoya University, Furo, Chikusa, Nagoya 464-8602, Japan su: Polycyclic aromatic hydrocarbons Organic compounds Density functionals Crystals Organic chemistry sug: subj: Polycyclic aromatic hydrocarbons Organic compounds Density functionals Crystals Organic chemistry ab: The article reports the new aromatic π systems, Pentaindenocorannulene and Tetraindenocorannulene. The procedures in the syntheses of the two new geodesic polyarenes are the same except in their starting organic compounds. The X-ray crystal structures and the degree of pyramidization were also examined. It was concluded that solution chemical methods can synthesize carbon-rich molecules. The use of density functional theory to calculate geometries for geodesic polyarenes is recommended. pubtype: Academic Journal doctype: Article src: R language: English refInfo: copyright: @attributes: flag: Y dt: @attributes: year: 2007 holdings: @attributes: islocal: N |
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