Discrete Thermal Patterns of Hydrogen and Deuterium Molecules Enclathrated in Confined Hydrate Cages.
The article reports on the synthesis of two different clathrate hydrates of THF + H and THF + D and comparison of their neutron diffraction patterns. It is indicated that the dissociation behaviors of H and D was examined by determining the diffraction sequences in different temperatures. Results sh...
| Published in: | Journal of the American Chemical Society Vol. 129; no. 8; pp. 2208 - 2210 |
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| Main Authors: | , , , , |
| Format: | Article |
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American Chemical Society
2/28/2007
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| Subjects: | |
| Online Access: | View this record in EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=24272073&site=ehost-live header: @attributes: shortDbName: hlh uiTerm: 24272073 longDbName: Humanities International Complete uiTag: AN controlInfo: bkinfo: jinfo: jid: 00027863 ACS jtl: Journal of the American Chemical Society issn: 00027863 maglogo: N pubinfo: dt: 2/28/2007 vid: 129 iid: 8 pid: 997 pub: American Chemical Society artinfo: ui: 24272073 10.1021/ja0674441 ppf: 2208 ppct: 2 formats: tig: atl: Discrete Thermal Patterns of Hydrogen and Deuterium Molecules Enclathrated in Confined Hydrate Cages. aug: au: Yong Nam Choi Sun-Hwa Yeon Youngjune Park Sukjeong Choi Huen Lee affil: Korea Atomic Energy Research Institute Korea Advanced Institute of Science and Technology su: Clathrate compounds Neutron diffraction Dissociation (Chemistry) Hydrates Temperature sug: subj: Clathrate compounds Neutron diffraction Dissociation (Chemistry) Hydrates Temperature ab: The article reports on the synthesis of two different clathrate hydrates of THF + H and THF + D and comparison of their neutron diffraction patterns. It is indicated that the dissociation behaviors of H and D was examined by determining the diffraction sequences in different temperatures. Results show that the major differences in the neutron scattering lengths are noted to be the cause for the unusual dissociation manner. pubtype: Academic Journal doctype: Article src: R language: English refInfo: copyright: @attributes: flag: Y dt: @attributes: year: 2007 holdings: @attributes: islocal: N |
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