Generation and Reactions of o-Bromophenyllithium without Benzyne Formation Using a Microreactor.
The article examines the reaction of o-Bromophenyllithium without benzyne formation using a microreactor. It is noted that an efficient way of controlling the generations and reactions of highly reactive intermediates can be accomplished by virtue of precise residence time control and temperature co...
| Publicado en: | Journal of the American Chemical Society Vol. 129; no. 11; pp. 3046 - 3048 |
|---|---|
| Autores principales: | , , , , , |
| Formato: | Artículo |
| Publicado: |
American Chemical Society
3/21/2007
|
| Materias: | |
| Acceso en línea: | Ver este registro en EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=24582585&site=ehost-live header: @attributes: shortDbName: hlh uiTerm: 24582585 longDbName: Humanities International Complete uiTag: AN controlInfo: bkinfo: jinfo: jid: 00027863 ACS jtl: Journal of the American Chemical Society issn: 00027863 maglogo: N pubinfo: dt: 3/21/2007 vid: 129 iid: 11 pid: 997 pub: American Chemical Society artinfo: ui: 24582585 10.1021/ja068330s ppf: 3046 ppct: 2 formats: tig: atl: Generation and Reactions of o-Bromophenyllithium without Benzyne Formation Using a Microreactor. aug: au: Usutani, Hirotsugu Tomida, Yutaka Nagaki, Aiichiro Okamoto, Hideho Nokami, Toshiki Yoshida, Jun-ichi affil: Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan su: Intermediates (Chemistry) Microreactors Temperature control Lithium Temperature sug: subj: Intermediates (Chemistry) Microreactors Temperature control Lithium Temperature ab: The article examines the reaction of o-Bromophenyllithium without benzyne formation using a microreactor. It is noted that an efficient way of controlling the generations and reactions of highly reactive intermediates can be accomplished by virtue of precise residence time control and temperature control inherent in microsystems. The microflow systems server as a powerful tool for mechanistic studies on reactions involving highly unstable intermediates such as o-bromophenyllithium. pubtype: Academic Journal doctype: Article src: R language: English refInfo: copyright: @attributes: flag: Y dt: @attributes: year: 2007 holdings: @attributes: islocal: N |
|---|