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Intermolecular Activation of C—X (X = H, O, F) Bonds by a Ti≡CBu Linkage.

The article discusses the intermolecular activation of C—X (X = H, O, F) bonds by a titanium alkylidyne (Ti≡CBu) linkage. It is stated that a strong C—X bonds can be activated by a highly polarized Ti≡C linkage. Moreover, the ability of the intermediates to intermolecularly cleave aryl C—O and C—F b...

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Publicado en:Journal of the American Chemical Society Vol. 129; no. 17; pp. 5302 - 5304
Autores principales: Bailey, Brad C., Huffman, John C., Mindiola, Daniel J.
Formato: Artículo
Publicado: American Chemical Society 5/2/2007
Materias:
Chemical bonds
Intermolecular forces
Titanium compounds
Chemical reactions
Chemical structure
Physical & theoretical chemistry
Acceso en línea:Ver este registro en EBSCOhost
Sumario:The article discusses the intermolecular activation of C—X (X = H, O, F) bonds by a titanium alkylidyne (Ti≡CBu) linkage. It is stated that a strong C—X bonds can be activated by a highly polarized Ti≡C linkage. Moreover, the ability of the intermediates to intermolecularly cleave aryl C—O and C—F bonds provides an opportunity to study a novel approach surrounding the cleavage of a strong C—heteroatom linkages.