Intermolecular Activation of C—X (X = H, O, F) Bonds by a Ti≡CBu Linkage.
The article discusses the intermolecular activation of C—X (X = H, O, F) bonds by a titanium alkylidyne (Ti≡CBu) linkage. It is stated that a strong C—X bonds can be activated by a highly polarized Ti≡C linkage. Moreover, the ability of the intermediates to intermolecularly cleave aryl C—O and C—F b...
| Published in: | Journal of the American Chemical Society Vol. 129; no. 17; pp. 5302 - 5304 |
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| Main Authors: | , , |
| Format: | Article |
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American Chemical Society
5/2/2007
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| Subjects: | |
| Online Access: | View this record in EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=25140494&site=ehost-live header: @attributes: shortDbName: hlh uiTerm: 25140494 longDbName: Humanities International Complete uiTag: AN controlInfo: bkinfo: jinfo: jid: 00027863 ACS jtl: Journal of the American Chemical Society issn: 00027863 maglogo: N pubinfo: dt: 5/2/2007 vid: 129 iid: 17 pid: 997 pub: American Chemical Society artinfo: ui: 25140494 10.1021/ja0684646 ppf: 5302 ppct: 2 formats: tig: atl: Intermolecular Activation of C—X (X = H, O, F) Bonds by a Ti≡CBu Linkage. aug: au: Bailey, Brad C. Huffman, John C. Mindiola, Daniel J. affil: Department of Chemistry and Molecular Structure Center, Indiana University, Bloomington, Indiana 47405 su: Chemical bonds Intermolecular forces Titanium compounds Chemical reactions Chemical structure Physical & theoretical chemistry sug: subj: Chemical bonds Intermolecular forces Titanium compounds Chemical reactions Chemical structure Physical & theoretical chemistry ab: The article discusses the intermolecular activation of C—X (X = H, O, F) bonds by a titanium alkylidyne (Ti≡CBu) linkage. It is stated that a strong C—X bonds can be activated by a highly polarized Ti≡C linkage. Moreover, the ability of the intermediates to intermolecularly cleave aryl C—O and C—F bonds provides an opportunity to study a novel approach surrounding the cleavage of a strong C—heteroatom linkages. pubtype: Academic Journal doctype: Article src: R language: English refInfo: copyright: @attributes: flag: Y dt: @attributes: year: 2007 holdings: @attributes: islocal: N |
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