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Imido Exchange in Bis(imido) Uranium(Vl) Complexes with Aryl Isocyanates.

The article discusses a study on the reactivity of Bismido Uranium Complexes toward aryl isocyanates. Evidences from density functional theory calculations and N-labeling studies are presented. Further investigation on the reactions of substituted carbodiimides and other unsaturated electrophiles to...

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Publicado en:Journal of the American Chemical Society Vol. 130; no. 10; pp. 2930 - 2932
Autores principales: Spencer, Liam P., Ping Yang, Scott, Brian L., Batista, Enrique R., Boncella, James M.
Formato: Artículo
Publicado: American Chemical Society 3/12/2008
Materias:
Density functionals
Uranium
Isocyanates
Functional analysis
Isocyanic acid
Acceso en línea:Ver este registro en EBSCOhost
Sumario:The article discusses a study on the reactivity of Bismido Uranium Complexes toward aryl isocyanates. Evidences from density functional theory calculations and N-labeling studies are presented. Further investigation on the reactions of substituted carbodiimides and other unsaturated electrophiles to generate imido reactivity is suggested.