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Imido Exchange in Bis(imido) Uranium(Vl) Complexes with Aryl Isocyanates.

The article discusses a study on the reactivity of Bismido Uranium Complexes toward aryl isocyanates. Evidences from density functional theory calculations and N-labeling studies are presented. Further investigation on the reactions of substituted carbodiimides and other unsaturated electrophiles to...

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Published in:Journal of the American Chemical Society Vol. 130; no. 10; pp. 2930 - 2932
Main Authors: Spencer, Liam P., Ping Yang, Scott, Brian L., Batista, Enrique R., Boncella, James M.
Format: Article
Published: American Chemical Society 3/12/2008
Subjects:
Density functionals
Uranium
Isocyanates
Functional analysis
Isocyanic acid
Online Access:View this record in EBSCOhost
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      dt: 3/12/2008
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      pub: American Chemical Society
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        10.1021/ja7107454
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        atl: Imido Exchange in Bis(imido) Uranium(Vl) Complexes with Aryl Isocyanates.
      aug:
        au:
          Spencer, Liam P.
          Ping Yang
          Scott, Brian L.
          Batista, Enrique R.
          Boncella, James M.
        affil:
          Materials, Physics and Applications Division, Los Alamos National Laboratory, MS J514, Los Alamos New Mexico, 87545
          Theoretical Division, Los Alamos National Laboratory, MS B268, Los Alamos New Mexico, 87545
      su:
        Density functionals
        Uranium
        Isocyanates
        Functional analysis
        Isocyanic acid
      sug:
        subj:
          Density functionals
          Uranium
          Isocyanates
          Functional analysis
          Isocyanic acid
      ab: The article discusses a study on the reactivity of Bismido Uranium Complexes toward aryl isocyanates. Evidences from density functional theory calculations and N-labeling studies are presented. Further investigation on the reactions of substituted carbodiimides and other unsaturated electrophiles to generate imido reactivity is suggested.
      pubtype: Academic Journal
      doctype: Article
      src: R
    language: English
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          year: 2008
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