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Ti(IV)-Centered Dynamic Interconversion between Pd(ll), Ti(IV)-Containing Ring and Cage Molecules.

The article describes the interconversion of between Pd(II), Ti(IV)-containing ring- and cage-shaped complexes triggered by Ti-centered coordination changes between a Ti(catecholato) and TiH(catecholato)(acac) structures. According to the authors, the conversion was found to take place reversibly by...

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Publicado en:Journal of the American Chemical Society Vol. 130; no. 31; pp. 10058 - 10060
Autores principales: Hiraoka, Shuichi, Sakata, Yoko, Shionoya, Mitsuhiko
Formato: Artículo
Publicado: American Chemical Society 8/6/2008
Materias:
Transition metal complexes
Palladium
Titanium
Coordination compounds
Molecular structure
Acceso en línea:Ver este registro en EBSCOhost
Sumario:The article describes the interconversion of between Pd(II), Ti(IV)-containing ring- and cage-shaped complexes triggered by Ti-centered coordination changes between a Ti(catecholato) and TiH(catecholato)(acac) structures. According to the authors, the conversion was found to take place reversibly by changing the basicity condition and the component fraction in solution.