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Ti(IV)-Centered Dynamic Interconversion between Pd(ll), Ti(IV)-Containing Ring and Cage Molecules.

The article describes the interconversion of between Pd(II), Ti(IV)-containing ring- and cage-shaped complexes triggered by Ti-centered coordination changes between a Ti(catecholato) and TiH(catecholato)(acac) structures. According to the authors, the conversion was found to take place reversibly by...

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Published in:Journal of the American Chemical Society Vol. 130; no. 31; pp. 10058 - 10060
Main Authors: Hiraoka, Shuichi, Sakata, Yoko, Shionoya, Mitsuhiko
Format: Article
Published: American Chemical Society 8/6/2008
Subjects:
Transition metal complexes
Palladium
Titanium
Coordination compounds
Molecular structure
Online Access:View this record in EBSCOhost
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      dt: 8/6/2008
      vid: 130
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      pub: American Chemical Society
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        10.1021/ja803115j
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        atl: Ti(IV)-Centered Dynamic Interconversion between Pd(ll), Ti(IV)-Containing Ring and Cage Molecules.
      aug:
        au:
          Hiraoka, Shuichi
          Sakata, Yoko
          Shionoya, Mitsuhiko
        affil:
          Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
          Precursory Research for Embryonic Science and Technology (PRESTO), Japan Science Technology Agency, 4-1-8 Honcho, Kawaguchi, Sairama 332-0012, Japan
      su:
        Transition metal complexes
        Palladium
        Titanium
        Coordination compounds
        Molecular structure
      sug:
        subj:
          Transition metal complexes
          Palladium
          Titanium
          Coordination compounds
          Molecular structure
      ab: The article describes the interconversion of between Pd(II), Ti(IV)-containing ring- and cage-shaped complexes triggered by Ti-centered coordination changes between a Ti(catecholato) and TiH(catecholato)(acac) structures. According to the authors, the conversion was found to take place reversibly by changing the basicity condition and the component fraction in solution.
      pubtype: Academic Journal
      doctype: Article
      src: R
    language: English
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          year: 2008
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