Nitrosyl Derivatives of Diiron(I) Dithiolates Mimic the Structure and Lewis Acidity of the [FeFe]-Hydrogenase Active Site.

This study probes the impact of electronic asymmetry of diiron(l) dithiolato carbonyls. Treatment of Fe(SCH)(CO)(PMe) compounds (n = 2, 3; x = 1, 2, 3) with NOBF gave the derivatives [Fe(SCH)(CO)(PMe)(NO)]BF, which are electronically unsymmetrical because of the presence of a single NO ligand. Where...

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Publicado en:	Journal of the American Chemical Society Vol. 130; no. 36; pp. 12021 - 12031
Autores principales:	Olsen, Matthew T., Bruschi, Maurizio, De Gioia, Luca, Rauchfuss, Thomas B., Wilson, Scott A.
Formato:	Artículo
Publicado:	American Chemical Society 9/10/2008
Materias:	Organoiron compounds Density functionals Enantiomers Electrons Electrophiles
Acceso en línea:	Ver este registro en EBSCOhost